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Catalog Luminescent Complexes - LigandsLuminescent Complexes - Ligands
 
 
Building Blocks   |   Ligands
 
These ligands provide a very useful scaffold for the synthesis of novel metal complexes with unusual photophysical properties. Organometallic coupling reactions using the bromine substituted ligands have been shown to generate compounds with extremely long lifetimes of luminescence and red luminescence beyond 700 nm.
 

Product Cat. No. Amount Price (EUR) Buy / Note Downloads
dppz FP-412 25 mg 137,50    Add this product to your notepad  
5-Brom-1,10-phenanthroline FP-431 25 mg 187,50    Add this product to your notepad  
5,6-Dibrom-1,10-phenanthroline FP-432 25 mg 132,50    Add this product to your notepad  
4,4'-Di-tert-butylbipyridine FP-433 100 mg 26,00    Add this product to your notepad  
[2,2'-Bipyridine]-4,4'-dicarboxylic acid FP-434 100 mg 78,00    Add this product to your notepad  
3,5,6,8-Tetrabromo-1,10-phenanthroline FP-435 100 mg 78,00    Add this product to your notepad  

Selected References

  • Cao et al. (2009) Dye-Sensitized Solar Cells with a High Absorptivity Ruthenium Sensitizer Featuring a 2-(Hexylthio)thiophene Conjugated Bipyridine. The Journal of Physical Chemistry. C 113 (15):6290
  • Chesneau et al. (2009) Efficient Access to a Versatile 5,6-Dithio-1,10-phenanthroline Building Block and Corresponding Organometallic Complexes. Organic Letters 11 (3):649
  • Manolikakes et al. (2008) An Efficient Silane-Promoted Nickel-Catalyzed Amination of Aryl and Heteroaryl Chlorides. The Journal of Organic Chemistry 73 (4):1429
  • Páez et al. (2008) Oxygen atom transfer photocatalyzed by molybdenum(VI)dioxodibromo-(4,4'-dicarboxylate-2,2'-bipyridine) anchored on TiO2. Catalysis Today 133-135:619
  • Schwalbe et al. (2008) Synthesis and characterisation of poly(bipyridine)ruthenium complexes as building blocks for heterosupramolecular arrays. European Journal of Inorganic Chemistry 21 :3310
  • Pikulski et al. (2007) Tunable Transition Metal–Ligand Complexation for Enhanced Elucidation of Flavonoid Diglycosides by Electrospray Ionization Mass Spectrometry. J Am Soc Mass Spectrom 18 (3):422
  • Rau et al. (2004) Regioselective functionalization of tetrabromophenanthroline-Ruthenium complexes. European Journal of Inorganic Chemistry 10 :2001
  • Santiago et al. (2003) Photochemical isomerization of trans- to cis-[RuCl2(dppb)(4,4'-X2-2,2'-bipy)] (X=–H, –NO2, –Me, –COOH, –SMe, –O=SMe, –Cl, –OMe) complexes. Polyhedron 22 (24):3205
  • Tynan et al. (2003) Coordination and hydrogen bonded networks featuring 4,4-dicarboxy-2,2-bipyridine (H2dcbp): structural characterisation of H2dcbp, [Co(dcbp)(H2O)4]·4H2O, and {[Cu(dcbp)(H2O)2]·2H2O}n. Dalton Transactions 7:1223
  • Denes et al. (1978) Polyhalogenation of nitrogen-containing heterocyclic compounds. III. Polybromo-1,10-phenanthrolines. Journal für Praktische Chemie (Leipzig) 320 (1):172
  • Mlochowski (1974) Reactivity of phenanthrolines. III. Bromination of phenanthrolines. Roczniki Chemii 48 (12):2145
  • Case (1951) Substituted 1,10-phenanthrolines. IV. Bromo derivatives. Journal of Organic Chemistry 16:941
 
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